کتابخانه

Title: Ziegler Catalysts: Recent Scientific Innovations and Technological Improvements | Author(s): Günther Wilke (auth.), Prof. Dr. Gerhard Fink, Prof. Dr. Rolf Mülhaupt, Prof. Dr. Hans H. Brintzinger (eds.) | Publisher: Springer | Year: 1995 Edition: 1 Language: English | Pages: 511 | Size: 13 MB | Extension: pdf

"The book can be thoroughly recommended not only for specialists in metal-catalyzed polymerization but also for everyone with interests in this area." - Angewandte Chemie

Table of contents :
Front Matter....Pages I-XIII
“Karl Ziegler — The Last Alchemist”....Pages 1-14
Patent Right Aspects in Connection with Four Decades of Ziegler Catalysts....Pages 15-34
Novel Polyolefin Materials and Processes: Overview and Prospects....Pages 35-55
The Role of MAO-Activators....Pages 57-82
New Isotactic Polypropylenes via Metallocene Catalysts....Pages 83-97
Isospecific Pseudo-Helical Zirconocenium Catalysts....Pages 99-109
Manipulation of the Ligand Structure as an Effective and Versatile Tool for Modification of Active Site Properties in Homogeneous Ziegler-Natta Catalyst Systems....Pages 111-147
Polymerization of Phenyl Substituted Cyclic Olefins with Metallocene/Aluminoxane Catalysts....Pages 149-158
The Relationship Between Kinetics and Mechanisms....Pages 159-179
Binuclear Titanocene and Zirconocene Cations with μ-Cl- and μ-CH 3 -Bridges in Metallocene-Based Ziegler-Natta Catalyst Systems—Solution-NMR Studies....Pages 181-197
Advances in Ziegler Catalysts....Pages 199-216
Stereochemistry of Polymerization of Some α-Olefins in the Presence of Ziegler-Type Catalysts....Pages 217-235
Models for the Explanation of the Stereospecific Behaviour of Ziegler — Natta Catalysts....Pages 237-249
Forcefield Calculations on Zirconocene Compounds....Pages 251-274
Theoretical Studies on Olefin Polymerization Using Group 4 Metallocene Catalysts....Pages 275-289
A Combined Density Functional and Molecular Mechanics Study on Olefin Polymerization by Metallocene Catalysts....Pages 291-315
Olefin Polymerization with Single Component Organoscandium and Organoyttrium Catalysts....Pages 317-331
Heterogeneous Metallocene Catalysts....Pages 333-342
Kinetic Studies on Propene Polymerization using Magnesium Dichloride Supported Ziegler — Natta Catalysts....Pages 343-362
Gas Phase Polymerization of α-Olefins with Ziegler — Natta and Metallocene Catalysts: a Comparison....Pages 363-386
The Microreactor Model-Guideline for PE-HD Process and Product Development....Pages 387-400
The Activation of Supported Vanadium Catalysts in Ethylene Polymerization....Pages 401-411
Advances in Propylene Polymerization with MgCl 2 Supported Catalysts....Pages 413-425
Effects of Electron Donors in Super High Activity Catalysts for Polypropylene....Pages 427-440
Stereo- and Enantioselective Polymerization of Olefins with Homogeneous Ziegler — Natta Catalysts....Pages 441-454
Enantiomorphic Sites and Stereospecific Polymerization of Chiral 1-Olefins....Pages 455-467
Recent Developments in the Synthesis of Functionalised Polymers via Living Ring-Opening Metathesis Polymerization....Pages 469-480
Palladium Catalysed Copolymerization of Carbon Monoxide with Olefins to Alternating Polyketones and Polyspiroketals....Pages 481-496
Breakthrough in Acetylene Polymerization....Pages 497-505
Back Matter....Pages 507-513